Characteristic IR Absorptions of Functional Groups

Principal diagnostic bands are in boldface.

Class, functional group Group frequency (cm-1) Relative absorption intensity
Alkanes, alkyl groups
C-H stretch
C-H bend
2980-2850
1470-1450, 1400- 1360
medium to strong
medium
Alkenes
=C-H stretch
C=C stretch
3090-3010
1680-1620
medium
very weak
(trans) to medium (cis,term)
Alkynes
≡C-H stretch
C≡C stretch
3300-3250
2250-2200
medium, (terminal alkynes only)
weak (internal) to medium (terminal)
Aromatics
C-H stretch
arom. C-C stretch
3100-3000
1630-1590, 1520-1480
medium
medium

Alcohols
O-H stretch
C-O stretch
3650-3300
1150-1030
strong, broad
strong
Amines
N-H stretch
3450-3280 weak to medium, broad
Ethers
C-O stretch
1140-1100 very strong
Aldehydes
"C-H stretch"
C=O stretch
2740-2720
1735-1720
medium
very strong
Ketones
C=O stretch
1725-1705 very strong
Carboxylic acids
O-H stretch
C=O stretch
3300-2400
1710-1680
strong, very broad
very strong
Carboxylic acid chlorides
C=O stretch
1810-1790 strong
Esters
C=O stretch
C-O-C stretch
1750-1735
1290-1180
very strong
very strong
Amides
N-H stretch
C=O stretch
3540-3380
1680-1640
medium, broad (prim. & sec. only)
very strong
Nitriles
C≡N stretch
2260-2240 weak